Ice Harbor Dam Hydroelectric Generator Maintenance

Ice Harbor Dam Approaches 20th anniversary with Ecolink Inc.

ice-harbor-dam-hydro-electric-generator

Ecolink Inc. recognizes the engineering, maintenance and environmental, health and safety staff at the Ice Harbor Lock and Dam for their continued support of our maintenance repair and overhaul cleaning compounds used to maintain their (3) three 90-megawatt units and (3) three 111-megawatt units for an installed power generating capacity of 603 megawatts and maximum capacity of 693 megawatts.

Safety and Environmental Protection at Ice Harbor Lock and Dam

With large hydroelectric generators almost 50 years old, our products Electron and Heavyweight have been ‘on the job’ for nearly 20 years. We  greatly appreciate the loyalty and applaud the commitment of the US Army Corp of Engineers to the safety and protection of their employees, the Snake River and Lake Sacajawea.

Special Offer for Ice Harbor Lock and Dam Employees

Ecolink Inc. is offering a 15% discount and FREE shipping for any new cleaner degreasers, degreaser chemicals or industrial solvent manufactured or distributed by Ecolink Inc.

We offer numerous alternatives to:

  • Chemtronics
  • Petroferm Inc.
  • CRC Industries
  • Safety Kleen
  • Inland Technologies
  • ZEP
  • LPS Laboratories
 
 

Call 800 886-8240 or email info@ecolink.com to discuss your current use of any of these or other manufacturer’s brand to switch and start saving. With over 200 products to choose from, including several new formulations not yet listed on the website, we feel certain we can expand upon the savings and safety improvements enjoyed for nearly 20 years. Chemist owned and operated, we offer guaranteed FREE samples, including FREE freight, to evaluate for a RISK-FREE evaluation.

About Ice Harbor Lock and Dam

Map of Washington highlighting Walla Walla County

Source: Wikipedia.org

Ice Harbor Lock and Dam is a hydroelectric, concrete, gravity dam on the Snake River in Walla Walla and Franklin counties in the U.S. state of Washington. The dam is located 8 miles (13 km) northeast of the town of Burbank and 12 miles (20 km) east of Pasco, river mile 9.2. Its name comes from a tiny bay in the river where boats once tied up to wait for upstream ice-jams to break up.[2]

Construction began in June 1955. The main structure and three generators were completed in 1961, with an additional three generators finished in 1976. Generating capacity is 603 megawatts, with an overload capacity of 693 MW. The spillway has ten gates and is 590 feet (180 m) long.

Ice Harbor Dam is part of the Columbia River Basin system of dams.

Inside the Dam on the South side of the river is a large visitor center that has been recently updated to include a new film “The Snake – River of Life” and a new modern interactive touch screen kiosk with information on the dam and recreational opportunities in the area. The visitor center also offers an excellent fish ladder viewing room where you can sit and observe the migration of Salmon, Steelhead, and Shad. Due to security, visitors must pass through the security gate to gain access.

Lake Sacajawea, named for Sacajawea, is formed behind the dam. The lake stretches to the base of Lower Monumental Dam, 32 miles (50 km) upstream. The Wallula Channel, formed from the backup of Snake River entering the Columbia River just southeast of Pasco, runs 10 miles (16 km) downstream from the base of the dam.

USBR Dams Maintained with Electron Solvent & Hypersolve

US Bureau of Reclamation: Electron Solvent & Hypersolve

If you are bidding on any USBR dam projects that specify the use of Electron solvent or denatured alcohol for wiping the rotor of a large hydroelectric generator, please call 800 886-8240 or email info@ecolink.com.

Grand Coulee Dam

Image via Wikipedia

Electron solvent is approaching its 20th anniversary and was originally approved by Siemens-Westinghouse and General Electric for their turbines and generators. We offer denatured alcohol in convenient 5-gal pail container size along with many other commodity chemicals used during the maintenance, repair, and overhaul of hydroelectric generators. However, if you prefer a non-flammable alternative with much more solvency than denatured alcohol or comparable industrial cleaners than we urge you to upgrade to Hypersolve™ as a safe, effective, and best-in-class npb solvent. When paired with Electron it delivers a 1-2 punch that knocks out even the most baked on, caked on dirt and soils.

Electron & Hypersolve™ helped maintain Grand Coulee Dam during Major Overhaul

After more than 10 years of cleaning critical components with Electron at Grand Coulee Dam, the engineers and electrical technicians were seeking a safer and more effective alternative to denatured alcohol. After a series of site visits and product compatibility testing, Hypersolve™ was approved and has been in use for over 3 years.

As recently as August 2009, Electron and Hypersolve™ played a significant role as part of a $2M multi-year contract for Grand Coulee Dam Third Powerplant Unit Overhaul. The six generating units in the Third Power Plant (TPP) have been in service since the mid-1970s. Age-related wear began to create problems, which resulted in increased power outages and reduced reliability.

The overhaul project will ensure continued operation of the power plant and provide a reliable source of hydroelectric power to the region. These efforts, along with Electron and Hypersolve™, will result in improved reliability of equipment; minimizing outage durations, and will reduce the likelihood and magnitude of increases to outage time.

Special Offer for USBR Dam Employees

Ecolink Inc. is offering a 15% discount and FREE shipping for any new cleaner degreasers, degreaser chemicals or industrial solvent manufactured or distributed by Ecolink Inc.

We offer numerous alternatives to:

  • Chemtronics
  • Petroferm Inc.
  • CRC Industries
  • Safety Kleen
  • Inland Technologies
  • ZEP
  • LPS Laboratories
 
 

Call 800 886-8240 or email info@ecolink.com to discuss your current use of any of these or other manufacturer’s brand to switch and start saving. With over 200 products to choose from, including several new formulations not yet listed on the website, we feel certain we can expand upon the savings and safety improvements enjoyed for nearly 20 years. Chemist owned and operated, we offer guaranteed FREE samples, including FREE freight, to evaluate for a RISK-FREE evaluation.

 
Grand Coulee Dam Statistics

Source: Wikipedia.org

  • Largest concrete dam and concrete structure in North America with 11,975,521 yd³ (9,155,942 m³) used[24]
  • Total length of dam: 5,223 ft (1,592 m)
  • Length of main dam: 3,867 ft (1,178 m)
  • Length of forebay dam: 1,170 ft (356 m)
  • Length of Wing Dam: 186 ft (56 m)
  • Hydraulic height: 380 ft (116 m)
  • Height of dam from bedrock: 550 ft (168 m)
  • Height above original streambed: 401 ft (122 m)
  • Reservoir Lake Roosevelt stretches for 151 mi (243 km)
  • Average release: 110,000 ft³/s (3,100 m³/s)
  • 4 power plants, 33 generators
  • Installed generating nameplate capacity: 6809 MW [24]
  • Annual energy production: 25 TWh in 2007[25] (varies with annual river flow)
  • Capacity factor: 41.9% in 2007
  • In 2007, Grand Coulee generated the second-most energy among US power facilities, after the Palo Verde Nuclear Power Plant at 26.78 TWh.[25] Palo Verde has a lower nameplate capacity but operates at a higher capacity factor, giving it slightly more annual output.

US Army Corps of Engineers Dams: d Limonene & NPB Solvents

United States Army Corps of Engineers seal

d Limonene & NPB Solvents Used to Maintain Hydroelectric Generators

If you are bidding on any Army Corps of Engineers project that have specified the use of Electron solvent or denatured alcohol for wiping the rotor of a large hydro electric generator, please call 800 563-1305 or email info@ecolink.com.

Electron solvent is approaching its 20th anniversary and was originally approved by Siemens-Westinghouse and General Electric for their turbines and generators. Ecolink Inc. offers denatured alcohol and other commodity chemicals used during the maintenance, repair, and overhaul of hydroelectric generators. However, if you prefer a non-flammable alternative with much more solvency than denatured alcohol or comparable industrial cleaners than we urge you to upgrade to Hypersolve™ as a safe, effective and best-in-class NPB solvent.
When paired with Electron it delivers a 1-2 punch that knocks out even the most baked on, caked on dirt and soils.

Special Offer for US Army Corps of Engineer Dam Employees

Ecolink Inc. offers a 15% discount and FREE shipping for any new cleaner degreasers, degreaser chemicals or industrial solvent manufactured or distributed by Ecolink Inc.

We offer numerous alternatives to:

  • Chemtronics
  • Petroferm Inc.
  • CRC Industries
  • Safety Kleen
  • Inland Technologies
  • ZEP
  • LPS Laboratories
 

Call 800 886-8240 or email info@ecolink.com to discuss your current use of any of these or other manufacturer’s brand to switch and start saving. With over 200 products to choose from, including several new formulations not yet listed on the website, we feel certain we can expand upon the savings and safety improvements enjoyed for nearly 20 years. Chemist owned and operated, we offer guaranteed FREE samples, including FREE freight, to evaluate for a RISK-FREE evaluation.

 
 

 

U.S. Army Corps of Engineers Operational Facts and Figures

Source: Wikipedia.org

  • One HQ, 8 Divisions, 2 Provisional Division, 45 Districts, 6 Centers, one active-duty unit, 2 Engineer Reserve Command
  • At work in more than 90 countries
  • Supports 159 Army installations and 91 Air Force installations
  • Owns and operates 609 dams
  • Owns and/or operates 257 navigation lock chambers at 212 sites
  • Owns and operates 24% of US hydropower capacity (3% of the total US electric capacity)
  • Operates and maintains 12,000 miles (19,000 km) of commercial inland navigation channels
  • Maintains 926 coast, Great Lakes, and inland harbors
  • Dredge 255,000,000 cubic yards (195,000,000 m3) annually for construction or maintenance
  • Nation’s number one provider of outdoor recreation with more than 368 million visits annually to 4,485 sites at 423 Corps projects (383 major lakes and reservoirs)
  • Total water supply storage capacity of 329,900,000 acre feet (4.069×1011 m3)
  • Average annual damages prevented by Corps flood risk management projects (1995-2004) of $21 billion (see “Civil works controversies” below)
  • Approximately 137 environmental protection projects under construction (September 2006 figure)
  • Approximately 38,700 acres (157,000,000 m2) of wetlands restored, created, enhanced, or preserved annually under the Corps’ Regulatory Program
  • Approximately $4 billion in technical services to 70 non-DoD Federal agencies annually
  • Completed (and continuing work on) thousands of infrastructure projects in Iraq at an estimated cost over $9 billion: school projects (324,000 students), crude oil production 3 million barrels per day (480,000 m3/d), potable water projects (3.9 million people (goal 5.2 million)), fire stations, border posts, prison/courthouse improvements, transportation/communication projects, village road/expressways, railroad stations, postal facilities, and aviation projects. More than 90 percent of the USACE construction contracts have been awarded to Iraqi-owned businesses – offering employment opportunities, boosting the economy, providing jobs, and training, promoting stability and security where before there was none. Consequently, the mission is a central part of the U.S. exit strategy.

MIL PRF 680, PD 680 alternatives – Low VOC Solvents

Environmental-Preferred Alternatives to MIL-PRF-680/P-D-680 Cleaner

Before you consider buying Safety Kleen’s QSOL 300, stop and consider your choices. While 1 of 3 approved prodcuts per the attached article recently published there are more alternatives under review. Effective April 15, 2010 Ecolink Inc. is the ONLY approved alternative to MIL PRF 680B with MIL PRF 680C Type V. This option is ideal for areas requiring LOW VOC solvents.  Call 800 886-8240 or email info@ecolink.com.


Pull together

March – April HTIS Bulletin
By Hem L. Tripathi, Chemical Engineer, Hazardous Minimization and Green Products, DSCR

Three products are now available that meet the requirements of MIL-PRF-32295 (Cleaner, Non-Aqueous, Low-VOC, HAP-Free). These field tested products are on a Qualified Products List (QPL), and can be used to clean weapon systems across DOD maintenance facilities as alternatives to MIL-PRF-680. Furthermore, they are less hazardous, safer to use and environmentally compliant.

Three National Stock Numbers (6850-01-576-2676 (1GL), 6850-01-576-2765 (5 GL CO) and 6850-01-576-2736 (55 GL DR) are assigned and authorized for use against the Type I requirements of MIL-PRF-32295.

In August 2007, the Defense Supply Center Richmond (DSCR) initiated a program to find chemical alternatives for the MIL-PRF-680/P-D-680 specifications.  These specifications contain volatile organic compounds (VOCs) that affect human health and impact the environment.  VOCs are organic chemical compounds that have sufficiently high vapor pressures under normal conditions to significantly vaporize, thereby entering the atmosphere.  They are released during cleaning operations and contribute to the formation of ground-level ozone (photochemical smog), damage vegetation, and potentially harm the lungs, liver and kidneys. The United States Environmental Protection Agency (EPA) regulates VOCs in the air, water, and the land.

MIL-PRF-680 and P-D-680 establish the requirements for the hydrocarbon-based solvents used for degreasing and cleaning machine parts of aircraft as well as the support equipment for maintenance.  There is no commercial specification available to cover these military applications.

The qualified products for MIL-PRF-680 and P-D-680 have VOC content of more than 750 grams per liter, well above the currently regulated level in certain states.  Solvent emissions are regulated locally as well as regionally, and the air pollution control districts in California have the most stringent requirements.  Several years ago, the San Joaquin Valley Air Pollution Control District (SJVAPCD) imposed restrictions limiting the VOC content in solvents to no greater than 25 grams per liter for immersion cleaning processes (unless the solvent is used in an airtight cleaning system).  Under this new rule, MIL-PRF-680 could no longer be allowed in solvent degreasing operations in the SJVAPCD.  Since MIL-PRF-680 and P-D-680 were the only materials authorized by the applicable maintenance manuals to clean engine parts, an approved alternative was necessary to meet the new environmental regulations.

Environmentally Cleaned Gears, Before and After

To identify solvent(s) that were less hazardous, safer to use, and environmentally compliant, DSCR’s Hazardous Material Minimization Program branch initiated a collaborative program with the Naval Air Systems Command (NAVAIR), Materials Engineering Division at Patuxent River, MD.  The program effort was divided into three major elements: 1) development of the specification, 2) laboratory testing of potential alternatives on cleaning performance as well as material compatibility, and 3) field testing of alternatives with authentic parts.

NAVAIR developed a new specification, MIL-PRF-32295, titled, “Cleaner, Non-Aqueous, Low-VOC, HAP-Free,” and published it on November 5, 2008, for cleaning aircraft components, ground support equipment, and other general applications.  Since the Aerospace National Emission Standards for Hazardous Air Pollutants (NESHAP) states that immersion-cleaning solvents and wipe-cleaning solvents must have vapor pressures less than 7 mm Hg and 45 mm Hg respectively, these limits were used to distinguish between Type I and Type II products. The cleaning effectiveness of the tested candidates led to further describing Type I products as being suitable for cleaning light soils such as oils and hydraulic fluids, and Type II products as being suitable for cleaning heavy soils such as greases and carbon residues.  The new specification required that the solvent(s) be free of hazardous air pollutants (HAP), effective on grease and oil, non-toxic, compatible with metals and non-metals, and safe to use.  It also could not contain more than 25 grams per liter of VOCs, and also be free of ozone depleting substances.

After a thorough evaluation of numerous commercially available products, NavAir’s Materials Engineering Division selected five products for laboratory testing by its Industrial and Operational Chemicals, Material Engineering Laboratories. These cleaners then were tested for cleaning efficiency, material compatibility, corrosion, hydrogen-embrittlement, and the other tests as required by the specification.  Of the five selected, three products (QSOL 300, Cyclo-147F, and SB32) met the Type 1 requirements of MIL-PRF-32295 .These products have vapor pressures as low as 1 mmHg, zero VOC contents; and meet the most stringent environmental regulatory requirements.  Research is in progress to find products that meet the specification’s Type II.

Field testing the cleaners involved determining the cleaning performance of the three candidates at various military sites (Navy, Air Force, US Marine Corps, and US Coast Guard) on authentic dirty parts associated with different weapon systems. Each cleaning solvent was tested side-by-side against the current MIL-PRF-680 Type II solvent for the duration of the test (that involved cleaning identical parts).  Based on the specific cleaning application, the candidates were utilized in various cleaning techniques, brush, immersion, and wipe-cleaning.  Photographs of the parts were taken before and after cleaning to compare the effectiveness of the tested cleaners to the control.  Listed below are the cleaners that provided successful results with positive feedback.

Product & Manufacturers Chart

For additional information on these studies, contact:

Dr. Hem L. Tripathi
Hazardous Minimization & Green Products Branch, Defense Supply Center Richmond, Richmond, VA 23297.
PH: 804-279-5727
eMail: hem.tripathi@dla.mil; or,

Dr. El Sayed Arafat
Materials Engineering Division, Naval Air Systems Command (NAVAIR)
Patuxent River, MD
PH: 301.342.8054
eMail: elsayed.arafat@navy.mil.

MIL-PRF-680B is Officially Replaced by MIL-PRF-680C

MIL-PRF-680B is officially replaced by MIL-PRF-680C

Effective April 15, 2010, MIL PRF 680B has been replaced with MIL-PRF-680C. The difference?

  • 145° F  Flashpoint
  • Decent solvency
  • SCAQMD and CARB compliant.  Southcoast measured the VOC content at 17 grams/liter
  • Compliant to MIL-PRF-680C Type V – this means approved for government/military use
  • Evaporates residue free

Finally MIL PRF 680 gets VOC compliant

Call 800 886-8240 to request a FREE sample and experience the performance and safety of Ecolink 250-SS.

For more information on the evolution of MIL PRF 680 revision A to revision B to revision C, please visit:
/info/mil-prf-680c/

NOTE:This draft, dated 5 Feb 10, prepared by the U.S. Army Tank Automotive Research & Development Engineering Center, has not been approved and is subject to modification. DO NOT USE FOR ACQUISITION PURPOSES.

MIL-PRF-680C PROPOSED SUPERSEDING MIL-PRF-680B 26 October 2006

PERFORMANCE SPECIFICATION
DEGREASING SOLVENT

This specification is approved for use by all Departments and Agencies of the Department of Defense.

1. SCOPE

1.1 Scope. This specification covers degreasing solvent that consists of five types of petroleum distillates. The different types are referred to as “Stoddard solvent”, “141 degrees Fahrenheit (°F) (60.6 degrees Celsius (°C)) solvent”, “200°F (93.3°C) solvent”, “141°F d-limonene blended solvent” and “Low VOC solvent”. They are used for degreasing of machine parts in equipment maintenance.

1.2 Classification. Degreasing solvents are of the following types (see 6.2).

Type I               – Low flash point (Stoddard solvent) (Military Symbol SD-1)

Type II             – High flash point (Military Symbol SD-2)

Type III            – Very high flash point (200°F) (Military Symbol SD-3)

Type IV            – High flash point with citrus odor (Military Symbol SD-4)

Type V             – Low VOC solvent (Military Symbol SD-5)

1.2.1 NATO classification:

Type I               – S-752

Type II             – S-753

Type III            – S-760

Type IV            – None

Type V              – None

2. APPLICABLE DOCUMENTS

2.1 General. The documents listed in this section are specified in sections 3, 4, and 5 of this specification. This section does not include documents cited in other sections of this specification or recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users are cautioned that they must meet all specified requirement documents cited in sections 3, 4, and 5 of this specification, whether or not they are listed.

2.2 Government documents.

2.2.1 Specifications, standards, and handbooks. The following specifications, standards, and handbooks form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract.

STANDARD

FEDERAL

FED-STD-791 – Lubricants, Liquid Fuels and Related Products; Methods of Testing (FTM).

(Unless otherwise indicated, copies of the above specifications, standards, and handbooks are available from the Document Automation and Production Service, 700 Robbins Avenue, Building 4D, Philadelphia, PA 19111-5094.

2.2.2 Other Government documents, drawings and publications. The following other Government documents, drawings, and publications form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract.

ENVIRONMENTAL PROTECTION AGENCY (EPA)

EPA Method 420.1             – Methods for Chemical Analysis of Water and Wastes
Total Recoverable in Water and Solids.

EPA Method 3585             – Method for Waste Dilution for Volatile Organics.

EPA Method 8260B – Method for Volatile Organic Compounds by Gas
Chromatography/ Mass Spectrometry (GC/MS).

(Application for copies should be addressed to the US EPA Headquarters, 401 M Street SW, mail code 3204, Washington, DC 20460 or at http://www.epa.gov).

SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT (SCAQMD)

SCAQMD Method 313            – Determination of Volatile Organic Compounds
(VOC) by Gas Chromatography/Mass Spectrometry (GC/MS).

(Application for copies should be addressed to the South Coast Air Quality Management District, 21865 Copley Drive, Diamond Bar, CA 91765 or at http://www.aqmd.gov)

2.3 Non-Government publications. The following document forms a part of this document to the extent specified herein. Unless otherwise specified, the issues of the documents which are DoD adopted are those listed in the issue of the DoDISS cited in the solicitation. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract.

AMERICAN SOCIETY FOR QUALITY (ASQ)

Z1.4            – Sampling Procedures and Tables for Inspection by Attributes (DoD
adopted).

(Application for copies should be addressed to the American Society for Quality, P.O. Box 3005, Milwaukee, WI 53201-3005 or at http://www.asq.org).

ASTM INTERNATIONAL

D 56             – Standard Test Method for Flash Point by Tag Closed Cup Tester

D 86             – Standard Test Method for Distillation of Petroleum Products at Atmospheric
Pressure

D 130             – Standard Test Method for Corrosiveness to Copper from Petroleum
Products by Copper Strip Test

D 156             – Standard Test Method for Saybolt Color of Petroleum Products (Saybolt
Chromometer Method)

D 235             – Standard Test Method for Mineral Spirits (Petroleum Spirits) (Hydrocarbon
Dry-Cleaning Solvent)

D 847             – Standard Test Method for Acidity of Benzene, Toluene, Xylenes, Solvent
Naphthas, and Similar Industrial Aromatic Hydrocarbons

D 1133 – Standard Test Method for Kauri-Butanol Value of Hydrocarbon Solvents

D 1296 – Standard Test Method for Odor of Volatile Solvents and Diluents

D 1298 – Standard Test Method for Density, Relative Density (Specific Gravity), or
API Gravity of Crude Petroleum and Liquid Petroleum Products by
Hydrometer Method

D 1353 – Standard Test Method for Nonvolatile Matter in Volatile Solvents for Use in
Paint, Varnish, Lacquer, and Related Products

D 2879 – Standard Test Method for Vapor Pressure-Temperature Relationship and
Initial Decomposition Temperature of Liquids by Isoteniscope

D 3257 – Standard Test Method for Aromatics in Mineral Spirits by Gas
Chromatography

D 4057 – Standard Practice for Manual Sampling of Petroleum and Petroleum
Products

D 4177 – Standard Practice for Automatic Sampling of Petroleum and Petroleum
Products

F 483             – Standard Test Method for Total Immersion Corrosion Test for Aircraft
Maintenance Chemicals

F 945             – Standard Test Method for Stress-Corrosion of Titanium Alloys by Aircraft
Engine Cleaning Materials

F 1110            – Standard Test Method for Sandwich Corrosion Test

(Application for copies should be addressed to ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959 or at http://www.astm.org).

SOCIETY OF AUTOMOTIVE ENGINEERS (SAE)

AMS-QQ-A-250 – Aluminum and Aluminum Alloy, Plate and Sheet (DoD
adopted).

AMS 2470             – Anodic Treatment of Aluminum Alloys Chrome Acid Process
(DoD adopted).

AMS M 3171             – Magnesium Alloy, Processes for Pretreatment and Prevention
of Corrosion on (DoD adopted).

AMS 4377             – Magnesium Alloy, Sheet and Plate 3.0A1-1.0Zn-0.20Mn
(AZ31B-H24) Cold Rolled, Partially Annealed

AMS 4911             – Titanium Alloy Sheet, Strip, and Plate, 6AI-4V Annealed

AMS 5046             – Carbon Steel Sheet, Strip, and Plate, (SAE 1020 and 1025)
Annealed

(Application for copies should be addressed to the Society of Automotive Engineers, Inc., 400 Commonwealth Drive, Warrendale, PA 15096-0001 or at http://www.sae.org).

2.4 Order of precedence. In the event of a conflict between the text of this specification and the references cited herein, the text of this specification takes precedence. Nothing in this specification, however, supersedes applicable laws and regulations unless a specific exemption has been obtained.

3. REQUIREMENTS

3.1 Qualification. Solvents furnished under this specification shall be products that are authorized by the qualifying activity for listing on applicable qualified products list before contract award (see 4.2 and 6.3). Any change in the formulation of a qualified product will necessitate its requalification.

3.2 Materials. The hydrocarbon solvent shall be a virgin grade or recycled solvent derived from petroleum distillates, fraction from reclaiming and re-refining processes, or a mixture of these fractions. The d-limonene and hydrocarbon blended solvent is permitted as a Type IV solvent. The EPA exempt materials and hydrocarbon blended solvent is also permitted as a Type V solvent. The resultant solvent must be produced in such a manner as is necessary to meet the specified requirements.

3.3 Appearance. The solvent shall be clear and free from suspended matter and undissolved water when observed at a temperature between 60.1 and 78.1°F (15.6 and 25.6 °C).

3.4 Toxicity. The solvent shall have no adverse effects on human health when used as intended (see 6.1 and 6.6).

3.5 Carcinogenicity. The solvent shall contain no chemicals listed as carcinogens (see 6.7). Any carcinogenic components in the solvent in a concentration of 0.1 percent (%) or greater by weight (wt) or volume (vol) will be regarded as the presence of a carcinogen in the solvent.

3.6 Hazardous Air Pollutants. The solvent shall contain no chemicals listed as Hazardous Air Pollutants (HAPs) (see 6.7). Any HAP components in the solvent in a concentration of 1.0 percent (%) or greater by weight (wt) or volume (vol) will be regarded as the presence of a HAP in the solvent. The product containing less than 1 % of HAP shall be considered as a HAP free solvent. For carcinogenic HAPs see 3.5.

3.7 Physical and chemical property requirements. The solvents shall conform to the physical and chemical requirements in Table I when tested as specified in Table II.

TABLE I. Degreasing solvent properties.

Characteristics Type I Type II Type III Type IV Type V
Flash point (pt) °C 38-60 61–92 93-116 61–92 61–92
Flash point (pt) °F (100-140) (141-198) (200-241) (141-198) (141-198)
Distillation, °C:
Initial boiling pt., minimum (min) 149 177 220 171 177
Dry point, °C, maximum (max) 208 212 300 240 212
Kauri-Butanol value 27 to 45 27 to 45 27 to 45 27 to 45 NR 4/
Aromatic content, vol %, max 1 1 1 1 1
Total phenol content, parts per million (ppm), max 0.5 0.5 0.5 0.5 0.5
Dichlorobenzene, milligrams per liter (mg/L), max Benzene, mg/L, max 0.50.5 0.50.5 0.50.5 0.50.5 0.50.5
Tetrachloroethylene, mg/L, max 0.7 0.7 0.7 0.7 0.7
Trichloroethylene, mg/L, max 0.5 0.5 0.5 0.5 0.5
Apparent specific gravity,60/60°F 0.754 to 0.820 0.754 to 0.820 0.754 to 0.820 0.754 to 0.820 0.754 to 0.820
Total chlorine content (ppm),Max 100 100 100 100 100
Non-volatile residue, (mg/100 mL), max 8 8 8 8 8
Color, min 25 25 25 25 25
Odor 1/ Low & non-residual Low & non-residual Low & non-residual Low & non-residual Low & non-residual
Corrosion, copper, max 2/ 1b 1b 1b 1b 1b
Sandwich corrosion, max 1 1 1 1 1
Total immersion corrosion 3/ Pass Pass Pass Pass Pass
Titanium stress corrosionAcidity No crackingNeutral No crackingNeutral No crackingNeutral No crackingNeutral No crackingNeutral
Doctor test Negative Negative Negative Negative Negative
Vapor pressure, millimeters of Mercury (mm Hg) @ 20oC, max 7.0 2.0 0.4 2.0 1.0
Soil cleaning test, %, min 85 85 85 85 85
VOC, g/l, max NR NR NR NR 25

1/ Samples of MIL-PRF-680C, Type III, having satisfactory low odor characteristics
shall be used as reference standards.

2/ Test for three hours at 100 °C (212oF).

3/ See 4.4.2

4/ Not required

4. VERIFICATION

4.1 Classification of inspections. The inspection requirements specified herein are
classified as follows:

a.            Qualification inspection (see 4.2)

b.            Conformance inspection (see 4.3).

4.1.1 Inspection conditions. Unless otherwise specified, all inspections shall be performed in accordance the test conditions specified in 4.2.

4.2 Qualification inspection. The qualification inspection shall consist of all tests specified herein. Failure of any test shall be cause for rejection.

4.3 Conformance inspection. Conformance inspection shall consist of a sample for tests (see 4.3.2), samples for examination of filled containers (see 4.3.3), and the tests specified in Table II except for sandwich corrosion, total immersion corrosion, and titanium stress corrosion.

4.3.1 Lot. A lot shall consist of solvents from one batch or tank offered for delivery at one time. If material cannot be identified by batch or lot, a lot shall consist of not more than 10 000 gallons offered for delivery at one time (see 6.2).

4.3.2 Sampling for tests. Sampling of a lot for test purposes shall be in accordance with ASTM D 4057 or D 4177.

4.3.3 Sample for examination of filled containers. A random sample of filled unit containers and a sample of shipping containers fully prepared for delivery shall be selected from each lot of solvent in accordance with ASQ Z1.4.

4.4 Methods of inspection.

4.4.1 Tests. Tests shall be performed in accordance with the applicable methods specified in Table II and 4.4.2 through 4.4.3 to determine conformance with the requirements specified in 3.6.

TABLE II. Test methods for inspections.

Characteristic ASTM Methods Other Methods
Flash Point D 56
Distillation D 86
Kauri-Butanol value D 1133
Aromatic content D 3257
Apparent specific gravity D 1298
Color D 156
Odor D 1296
Non-volatile residue D 1353
Copper Corrosion D 130
Sandwich corrosion F 1110
Total immersion corrosion F 483
Titanium stress corrosion F 945
Acidity D 847
Doctor test D 235
Vapor Pressure D 2879
Total phenol content EPA 420.1
Total dichlorobenzene content EPA 3585 and 8260B
Total benzene content EPA 3585, 8260B
Total trichloroethylene EPA 3585, 8260B
Total tetrachloroethylene EPA 3585, 8260B
Soil cleaning test FTM 791.7502
VOC test SCAQMD 313

4.4.2 Total immersion corrosion. The solvents shall not show any indication of staining, etching, pitting, or localized, or cause weight change to an average of three (3) test panels greater than that shown in Table III.

TABLE III. Alloy and maximum average weight loss.

Alloy Average of 3 panels wt. loss, max milligrams per square centimeter (mg/cm2/168 hrs)
Magnesium (AZ 31B-H24) AMS 4377 surface treated in accordance with AMS-M-3171, Type III 0.50
Aluminum, AMS-QQ-A-250, T3 surface, treatment in accordance with AMS 2470 0.15
Titanium, AMS 4911, 6AL-4V 0.10
Steel, AMS 5046, Grade 1020 0.25

4.4.3 Soil cleaning test. The test shall be conducted according to the solvent soil test method described in the appendix. The soil used in this evaluation is MIL-PRF-10924 grease. The acceptable limit for each type of solvent is defined in Table I.

4.4.4 Total chlorine content. The total chlorine content of the solvent shall be determined by a gas chromatographic method, microcoulometric or by the use of a portable test kit for the quantitative analysis of chlorine (see 6.6). Nonconformance to Table I shall constitute failure of this test.

5. PACKAGING

5.1 Packaging. For acquisition purpose, the packaging requirements shall be as specified in the contract or order (see 6.2). When actual packaging of materiel is to be performed by DoD personnel, these personnel need to contact the responsible packaging activity to ascertain requisite packaging requirements. Packaging requirements are maintained by the Inventory Control Point’s packaging activity with the Military Department or Defense Agency, or within the Military Department’s System Command. Packaging data retrieval is available from the managing Military Department’s or Defense Agency’s automated packaging files, CD-ROM products, or by contracting the responsible packaging activity.

6. NOTES

(This section contains information of a general or explanatory nature that may be helpful, but is not mandatory.)

6.1 Intended use. These solvents are hydrocarbon-based solvents and are used as degreasers and cleaners for painted or unpainted metal parts. However, the compatibility between existing paints and solvents should be verified prior to use. It is recommended that these solvents should be used with an appropriate recirculated parts washer. No other commercial specification is available to cover these military applications.

6.1.1 Type I. Type I (Stoddard solvent) is intended for use where a low odor solvent with fast drying characteristics is desired. This solvent is currently defined as a flammable material due to its low flash point. It is recommended that the alternative solvents for Type I are Types II, III and IV. When Type I solvent is used indoors, ventilation should be sufficient to prevent the accumulation of vapors above allowable limits.

6.1.2 Type II. Type II (low odor with high flash point solvent) is intended for use where a solvent with a higher flash point is desired. It is recommended over Type I for safety and regulatory reasons. When Type II solvent is used indoors, ventilation should be sufficient to prevent the accumulation of vapors above allowable exposure limits.

6.1.3 Type III. Type III (low odor with very high flash point solvent) is intended to be used where confined atmospheric conditions require a cleaner that conforms to the Federal Government’s directives for reduced hazardous materials.

6.1.4 Type IV. Type IV (citrus odor with high flash point) is intended for use where a solvent with a high flash point and strong solvency is desired. This solvent is formulated with petroleum based hydrocarbon solvents and d-limonene additive. When Type IV solvent is used indoors, ventilation should be sufficient to prevent the accumulation of vapors above allowable exposure limits.

6.1.5 Type V.  Type V (Low VOC solvent) is intended for use where solvent confined atmospheric conditions require a cleaner that conforms to the Federal and Local Government’s directives for reducing VOC of solvent.

6.2 Acquisition requirements. Acquisition documents must specify the following:

a.            Title, number and date of this specification.

b.            Type and quantity (see 1.2. and 4.3.1).

c.            Issue of DODISS to be cited in the solicitation, and if required, the specific issue of individual documents referenced (see 2.2.1 and 2.3).

d.            Packaging requirements (see 5.1)

6.3 Qualification. With respect to products requiring qualification, awards will be made only for products which are at the time of award of contract, qualified for inclusion in Qualified Product List QPL No. 680 whether or not such products have actually been so listed by that date. The attention of the contractors is called to these requirements, and manufacturers are urged to arrange to have the products that they propose to offer to the Federal Government tested for qualification in order that they may be eligible to be awarded contracts or purchase orders for the products covered by this specification.

6.3.1 Specification preparing activity. Information and instructions regarding qualification inspection under this specification may be obtained from the Department of the Army, TACOM-TARDEC, ATTN: AMSRD-TAR-E/268, 6501 E. 11 Mile Road, Warren, MI 48397-5000.

6.4 International standardization. Certain provisions of this specification are the subject of international standardization agreement (NATO STANAG 1135, ANNEX C). When amendment, revision, or cancellation of this specification is proposed which would affect or violate the international agreement concerned, the preparing activity will take appropriate reconciliation action through international channels, including departmental standardization offices, if required.

6.5 Disposal actions. Disposal of this product should be in accordance with local, state and Federal regulations. Care should be taken to avoid mixing used MIL-PRF-680 with other waste materials, especially those containing halogenated solvents. However, these solvents can be recycled instead of disposal.

6.6 Material Safety Data Sheets. Contracting officers will identify those activities requiring copies of completed Material Safety Data Sheets (MSDSs) prepared in accordance with FED-STD-313. The pertinent Government mailing addresses for submission of data are listed in FED-STD-313; and 29 CFR 1910.1200 requires that the MSDS for each hazardous chemical used in an operation must be readily available to personnel using the material. Contracting officers will identify the activities requiring copies of the MSDS (see 3.4 and 4.4.4).

6.7 Definitions.

6.7.1 Carcinogens. The Occupational Safety and Health Administration (OSHA) definition of carcinogens are those chemicals / processes appearing in lists 1, 2A, and 2B of the International Agency for Research on Cancer (IARC) 1/; substances known to be carcinogenic and occupational exposures associated with a technological process known to be carcinogenic by the National Toxicology Program (NTP) Report on Carcinogens (latest annual report) 2/; and OSHA regulated carcinogens.

6.7.2. Hazardous Air Pollutant (HAP). HAP is defined as any substance listed under Section 112 of the Clean Air Act or its modifications. The text of the Clean Air Act, listed pollutants and modifications are kept by the Environmental Protection Agency (EPA) and are accessible through the website: http://www.epa.gov

1/            Copies of these volumes may be found in medical libraries or through the World Health Organization, 1211 Geneva 27, Switzerland.

2/            Copies may be obtained from the Public Health Service, National Toxicology Program, Public Information Office, P.O. Box 12233, MD B2-04, Research Triangle Park, NC 27709 or at http://ntp-server.niehs.nih.gov

6.8 Subject term (key word) listing.

d-limonene

d-limonene/hydrocarbon blended solvent (type IV)

Mineral Spirits

Naphtha

Petroleum Spirits (USA)

Stoddard Solvent (type I)

141 F Solvent (type II)

200 F Solvent (type III)

Low VOC Solvent (type V)

6.9 Changes from previous issues. Marginal notations are not used in this revision to identify changes with respect to the previous issue due to the extensiveness of the changes.

Custodians: Army – AT                                    Preparing Activity:

Air Force – 68 Navy – AS                                    Army – AT

(Project 6850-2010-007)

Review Activities:

Army – AV, EA, MD1, MI, MR, SM

Air Force – 03, 11, 50

Navy – MC, SH

DLA – GS, GS3, DP

DTRA – DS

GSA/GSS – 7FLE

MISC – MP

NOTE: The activities listed above were interested in this document as of the date of this document.